Mechanochemical synthesis of aromatic ketones: pyrylium tetrafluoroborate mediated deaminative arylation of amides

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dc.contributor.authorMkrtchyan, Satenik
dc.contributor.authorShalimov, Oleksandr O.
dc.contributor.authorGarcia, Michael G.
dc.contributor.authorZapletal, Jiří
dc.contributor.authorIaroshenko, Viktor O.
dc.date.accessioned2025-07-04T10:04:02Z
dc.date.available2025-07-04T10:04:02Z
dc.date.issued2024
dc.descriptionIn: Chemical Science. Cambridge : Royal Society of Chemistry, 2024. ISSN 2041-6520. Vol. 15, no. 24 (2024), pp. 9155-9163.
dc.description.abstractA new method has been introduced that is able to tackle the complexities of N–C(O) activation in amide moieties through utilization of pyrylium tetrafluoroborate in a mechanochemical setting, where amide bonds undergo activation and subsequent conversion to biaryl ketones. Due to the employment of a mechanochemical setting, the reaction conforms to green chemistry principles, offering an environmentally friendly approach to traditional amide derivatization techniques that rely on transition metals to achieve further functionalization.
dc.description.sponsorshipAPVV-21-0362 Perfluóralkylácia - stratégia diverzifikácie komplexných organických molekúl v neskorej fáze syntézy
dc.identifier.doihttps://doi.org/10.1039/d4sc00904e
dc.identifier.issn2041-6520
dc.identifier.issn2041-6539
dc.identifier.urihttps://repo.umb.sk/handle/123456789/698
dc.language.isoen
dc.publisherRoyal Society of Chemistry : Cambridge
dc.rightsCC BY Creative Commons Attribution 4.0. International
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectmechanochémia
dc.subjectmechanochemistry
dc.subjectketóny
dc.subjectorganická chémia
dc.subjectorganic chemistry
dc.subjectfarmaceutický priemysel
dc.subjectpharmaceutical industry
dc.titleMechanochemical synthesis of aromatic ketones: pyrylium tetrafluoroborate mediated deaminative arylation of amides
dc.typeArticle
dc.typeinfo:eu-repo/semantics/article

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