Nanocellulose as a reaction media and stoichiometric reagent for FeCl3-mediated reductive functionalization of nitro compounds

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dc.contributor.authorMkrtchyan, Satenik
dc.contributor.authorPurohit, Vishal
dc.contributor.authorZapletal, Jiří
dc.contributor.authorShalimov, Oleksandr O.
dc.contributor.authorIaroshenko, Viktor O.
dc.date.accessioned2025-06-18T05:25:00Z
dc.date.available2025-06-18T05:25:00Z
dc.date.issued2024
dc.descriptionIn: ACS Sustainable Chemistry & Engineering. Washington : The American Chemical Society, 2024. ISSN 2168-0485. Vol. 12, no. 1 (2024), pp. 1-9.
dc.description.abstractAmong a wide array of synthetic amides, N-aryl/alkyl amides are an important class of structural motifs having significant importance in pharmaceutical and agrochemical industries. In this regard, a rapid, low-cost, and environmentally friendly synthesis of N-aryl/alkyl amides still remains in a high demand. Herein, we report a convenient route for the mechanochemical synthesis of N-aryl/alkyl amides via FeCl3-catalyzed reductive amidation of nitro compounds, as well as acylation of aliphatic/aromatic amines with carboxylic acids using nanocellulose as the reaction media/stoichiometric reducing agent. The protocol was found to be simple, efficient, and environmentally benign to obtain a diverse array of the respective amides with good to excellent yields. Furthermore, the use of nitro compounds, amines, and carboxylic acids as cheap and readily available starting materials, FeCl3 as a nontoxic catalyst, and nanocellulose as the biodegradable reaction media as well as the stoichiometric reducing agent makes this protocol in the category of a green chemical transformation.
dc.description.sponsorshipAPVV-21-0362 Perfluóralkylácia - stratégia diverzifikácie komplexných organických molekúl v neskorej fáze syntézy
dc.identifier.doihttps://doi.org/10.1021/acssuschemeng.3c04372
dc.identifier.issn2168-0485
dc.identifier.urihttps://repo.umb.sk/handle/123456789/640
dc.language.isoen
dc.publisherThe American Chemical Society : Washington
dc.rightsCC BY Creative Commons Attribution 4.0. International
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectmechanochémia
dc.subjectmechanochemistry
dc.subjectnitrozlúčeniny
dc.subjectnitro compounds
dc.subjectkatalýza
dc.titleNanocellulose as a reaction media and stoichiometric reagent for FeCl3-mediated reductive functionalization of nitro compounds
dc.typeArticle
dc.typeinfo:eu-repo/semantics/article

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